Journal article
Pulse radiolysis of pyridine and methylpyridines in aqueous solutions
In
Radiation Physics and Chemistry
—
1993, Volume 41, Issue 6, pp. 825-834
Abstract
The radicals formed from pyridine, 3-methylpyridine, 3,5-dimethylpyridine, 2,6-dimethylpyridine and 2,4,6-trimethylpyridine by attack of H, e(aq)-, OH and O.- in aqueous solutions were investigated by pulse radiolysis in the pH-range 1-13.8. The UV-vis. absorption spectra as well as the formation and decay kinetics for the protonated and unprotonated forms of the methylpyridine radicals studied are presented.
The pK(a)-values for the OH-adducts were determined.
| Language: | English |
|---|---|
| Year: | 1993 |
| Pages: | 825-834 |
| ISSN: | 0969806x and 18790895 |
| Types: | Journal article |
| DOI: | 10.1016/0969-806X(93)90028-S |
