Journal article
Aftereffects of the cobalt-57-iron-57 electron-capture reaction in cobalt-57-doped tricadmium bis[hexacyanoferrate(III)] dodecahydrate
Mössbauer-emission spectra of cobalt-57-doped Cd3[Fe(CN)6]2, 12H2O have been recorded at various temperatures and resolved into two doublets, one symmetric for the parent [Fe(CN)6]3– and one asymmetric attributed to a square-pyradimal [Fe(CN)5]2– complex. The asymmetry vanishes with increasing temperature and thus cannot be attributed to a Goldanskii–Karyagin effect.
The possibilities of paramagnetic relaxation are briefly discussed.
Language: | English |
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Year: | 1974 |
Pages: | 2309-2310 |
ISSN: | 14779226 , 14727773 , 13645447 and 03009246 |
Types: | Journal article |
DOI: | 10.1039/dt9740002309 |