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1 Book chapter

Kinetics of Methyl Radicals Studied by Pulse Radiolysis Combined with Infrared Diode Laser Spectroscopy

Pagsberg, Palle Bjørn; Ratajczak, E.; Sillesen, A.

Kinetics and Mechanism of Elementary Chemical Processes of Importance in Combustion. 5. Co-ordinators Periodic Report for the Period 1 Oct 1987 To 31 Mar 1988 — 1989

Year: 1989

Language: English

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2 Journal article

Kinetics of the addition reaction of methyl radicals with nitric oxide studied by pulse radiolysis combined with infrared diode laser spectroscopy

Jodkowski, J.T.; Ratajczak, E.; Sillesen, A.; Pagsberg, P.

Chemical Physics Letters — 1993, Volume 203, Issue 5-6, pp. 490-496

The reaction CH3 + NO (+ M) --> CH3NO ( + M) was initiated by pulse radiolysis of acetone/nitric oxide mixtures and the kinetics of methyl radicals was studied by time-resolved infrared absorption spectroscopy. The rate constant was found to be strongly pressure dependent in the range of p (M

Year: 1993

Language: English

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