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Journal article

Asymmetric Synthesis via Chiral Aziridines

In Acta Chem. Scand — 1996, Volume 50, pp. 361-368

By Tanner, David Ackland1; Harden, Adrian2; Wyatt, Paul2; Andersson, Pher G.2; Johansson, Fredrik2

From

Department of Organic Chemistry, Technical University of Denmark1

Uppsala University2

A series of chiral bis(aziridines) has been synthesised and evaluated as chelating ligands for a variety of asymmetric transformations mediated by metals [Os (dihydroxylation), Pd (allylic alkylation) Cu (cyclopropanation and aziridination, Li (1,2-addition of organolithiums to imines)]. In the best cases, an enantiomeric excess >95% was obtained.

Language: English
Year: 1996
Pages: 361-368
ISSN: 0904213x
Types: Journal article
ORCIDs: Tanner, David Ackland

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