Journal article
Process integration for the conversion of glucose to 2,5-furandicarboxylic acid
Novozymes A/S1
Sustainable and Green Chemistry, Department of Chemistry, Technical University of Denmark2
Department of Chemical and Biochemical Engineering, Technical University of Denmark3
Department of Chemistry, Technical University of Denmark4
Center for BioProcess Engineering, Department of Chemical and Biochemical Engineering, Technical University of Denmark5
The development of biorefineries means that a key feedstock for many new processes will be sugars in various forms, such as glucose or fructose. From these feedstocks a range of chemicals can be synthesized using heterogeneous catalysis, immobilized enzymes, homogeneous catalysts, soluble enzymes, fermentations or combinations thereof.
This presents a particularly interesting process integration challenge since the optimal conditions for each conversion step will be considerably different from each other. Furthermore, compared to oil-based refineries the feedstock represents a relatively high proportion of the final product value and therefore yield and selectivity in these steps are of crucial importance.
In this paper using the conversion of glucose to 2,5-furandicarboxylic acid and associated products as an example, alternative routes will be compared with respect to achievable selectivity, and achievable yield.
Language: | English |
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Year: | 2009 |
Pages: | 1318-1327 |
ISSN: | 17443563 and 02638762 |
Types: | Journal article |
DOI: | 10.1016/j.cherd.2009.06.010 |
ORCIDs: | Kegnæs, Søren , Riisager, Anders and Woodley, John |