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Journal article

Heteropoly acid promoted V2O5/TiO2 catalysts for NO abatement with ammonia in alkali containing flue gases

From

Department of Chemistry, Technical University of Denmark1

Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark2

CHEC Research Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark3

Department of Chemical and Biochemical Engineering, Technical University of Denmark4

V2O5/TiO2 and heteropoly acid promoted V2O5/TiO2 catalysts were prepared and characterized by N2 physisorption, XRPD and NH3-TPD. The influence of the calcination temperature from 400 to 700 1C on crystallinity and acidic properties was studied and compared with the activity for the selective catalytic reduction (SCR) of NO with ammonia.

The SCR activity of heteropoly acid promoted catalysts was found to be much higher than for unpromoted catalysts. The stability of heteropoly acid promoted catalysts is dependent on calcination temperature and there is a gradual decrease in SCR activity and acidity with increase in calcination temperatures.

Furthermore, the heteropoly acid promoted V2O5/TiO2 catalysts showed excellent alkali deactivation resistance and might therefore be alternative deNOx catalysts in biomass fired power plants.

Language: English
Year: 2011
Pages: 631-637
ISSN: 20444761 and 20444753
Types: Journal article
DOI: 10.1039/c1cy00081k
ORCIDs: Putluru, Siva Sankar Reddy , Jensen, Anker Degn , Riisager, Anders and Fehrmann, Rasmus

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