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Journal article

Thermal annealing in neutron-irradiated tribromobenzenes

By Siekierska, K.E.1,2; Halpern, A.3; Maddock, A. G.4

From

Risø National Laboratory, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

Institute of Nuclear Research3

University of Cambridge4

The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique.

The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.

Language: English
Year: 1968
Pages: 1645-1651
ISSN: 20505582 and 00224944
Types: Journal article
DOI: 10.1039/J19680001645

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