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Journal article · Conference paper

Undercooling and demixing in rapidly solidified Cu-Co alloys

From

Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Materials Research Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

Nano-Microstructures in Materials, Materials Research Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark3

Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark4

Electroceramics, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark5

The Cu–Co system displays a metastable miscibility gap in the liquid state. A considerable amount of work has been performed to study phase separation and related microstructures showing that demixing of the liquid is followed by coagulation before dendritic solidification. Due to kinetic competition of transformation phenomena, the mechanisms have not been fully disclosed.

This contribution reviews such findings with the help of a computer calculation of the phase diagram and extends the present knowledge by presenting new results obtained by rapidly solidifying various Cu–Co compositions using a wide range of cooling rates achieved by forcing the liquid into cylindric and conic moulds and by melt spinning.

Language: English
Year: 2007
Pages: 7-11
Proceedings: 12th International Conference on Rapidly Quenched and Metastable Materials
ISSN: 18734936 and 09215093
Types: Journal article and Conference paper
DOI: 10.1016/j.msea.2006.02.246
ORCIDs: Pryds, Nini

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