Journal article
Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K
In
Chemical Physics Letters
—
1993, Volume 207, Issue 4-6, pp. 498-503
Abstract
Rate constant ratios of the reactions of CF3O radicals with a number of hydrocarbons have been determined at 298 +/- 2 K and atmospheric pressure using a relative rate method. Using a previously determined value k(CF30 + C2H6) = 1.2 x 10(-12) cm3 molecule-1 s-1 these rate constant ratios provide estimates of the rate constants: k(CF3O + CH4) = (1.2 +/- 0.1) x 10(-14), k(CF3O + c-C3H6) = (3.6 +/- 0.2) x 10(-13), k(CF3O + C3H8) = (4.7 +/- 0.7) x 10(-12), k(CF3O + (CH3)3CH) = (7.2 +/- 0.5) x 10(-12), k(CF3O + C2H4) = (3.0 +/- 0.1) x 10(-11) and k(CF3O + C6H6) = (3.6 +/- 0.1) x 10(-11) cm3 molecule-1 s-1.
The importance of the reactions of CF3O radicals with hydrocarbons under atmospheric conditions is discussed.
| Language: | English |
|---|---|
| Year: | 1993 |
| Pages: | 498-503 |
| ISSN: | 18734448 and 00092614 |
| Types: | Journal article |
| DOI: | 10.1016/0009-2614(93)89036-H |
| ORCIDs: | 0000-0002-0088-3937 |
