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10 items by relevance
1 Journal article

Neutron diffraction and TSDC on Ba1−xUxF2+2x solid electrolytes

Ouwerkerk, M.; Andersen, N. H.; Veldkamp, F. F.; Schoonman, J.

Solid State Ionics — 1986, Volume 18-19, pp. 916-921

The defect structure of fluorite-type Ba1−xUxF2+2x solid solutions, which exhibit fast fluoride ion conductivity, has been investigated by quasi-elastic diffuse neutron scattering (QDNS) experiments, and thermally stimulated depolarisation current (TSDC) measurements. A comparison with model calculations reveals (212) clusters to dominate the defect structure. From 10 to 400K TSDS spectra reveal for x <0.05 six relaxation peaks of dipolar nature, along with the relaxation of macroscopic space charge. Conductivity parameters calculated from the latter relaxation compare very well with tho...

Year: 1986

Language: English

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p jgiadm bocnekfhl
2 Journal article

Neutron diffraction and TSDC on Ba1−xUxF2+2x solid electrolytes

Ouwerkerk, M.; Andersen, N.H.; Veldkamp, F.F.; Schoonman, J.

Solid State Ionics — 1986, Volume 18, Issue 18, pp. 916-921

The defect structure of fluorite-type Ba1−xUxF2+2x solid solutions, which exhibit fast fluoride ion conductivity, has been investigated by quasi-elastic diffuse neutron scattering (QDNS) experiments, and thermally stimulated depolarisation current (TSDC) measurements. A comparison with model calculations reveals (212) clusters to dominate the defect structure. From 10 to 400K TSDS spectra reveal for x < 0.05 six relaxation peaks of dipolar nature, along with the relaxation of macroscopic space charge. Conductivity parameters calculated from the latter relaxation compare very well with th...

Year: 1986

Language: English

More...
oj andekfc igbhlpm

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