Journal article
Absolute rate constants for the reaction of CF3O2 and CF3O radicals with NO at 295 K
In
Chemical Physics Letters
—
1993, Volume 206, Issue 1-4, pp. 369-375
Abstract
Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO2 and FNO absorption transients, rate constants for reaction between CF3O and CF3O2 radicals with NO were determined, CF3O2+NO-->CF3O+NO2 (3), CF3O+NO-->CF2O+FNO (5). k3 was derived to be (1.68+/-0.26)x10(-11) cm3 molecule-1 s-1, and k5=(5.2+/-2.7)x10(-11) cm3 molecule-1 s-1.
Results are discussed in the context of the atmospheric chemistry of halocarbons.
| Language: | English |
|---|---|
| Year: | 1993 |
| Pages: | 369-375 |
| ISSN: | 18734448 and 00092614 |
| Types: | Journal article |
| DOI: | 10.1016/0009-2614(93)85567-8 |
| ORCIDs: | 0000-0002-0088-3937 |
