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Journal article

Intrinsic resonance representation of quantum mechanics

From

Harvard University1

Physical Chemistry, Department of Chemistry, Technical University of Denmark2

Department of Chemistry, Technical University of Denmark3

The choice of basis states in quantum calculations can be influenced by several requirements, and sometimes a very natural basis suggests itself. However often one retreats to a ''merely complete'' basis, whose coefficients in the eigenstates carry Little physical insight. We suggest here an optimal representation, based purely on classical mechanics. ''Hidden'' constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leaving the quantum effects to be isolated and included by small matrix diagonalizations.

This simplifies the hierarchical structure of couplings between ''zero-order'' states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamilton-Jacobi equation. (C) 1997 American Institute of Physics.

Language: English
Publisher: American Institute of Physics
Year: 1997
Pages: 8564-8571
ISSN: 10897690 and 00219606
Types: Journal article
DOI: 10.1063/1.473911
ORCIDs: Møller, Klaus Braagaard

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