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Journal article

Effect of Cold Sintering Process (CSP) on the Electro-Chemo-Mechanical Properties of Gd-doped Ceria (GDC)

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Functional Oxides, Department of Energy Conversion and Storage, Technical University of Denmark2

University of Copenhagen3

Electron matter interaction, Nanocharacterization, National Centre for Nano Fabrication and Characterization, Technical University of Denmark4

Nanocharacterization, National Centre for Nano Fabrication and Characterization, Technical University of Denmark5

National Centre for Nano Fabrication and Characterization, Technical University of Denmark6

Southwest Jiaotong University7

Friedrich-Alexander University Erlangen-Nürnberg8

In this report, the effect of the cold sintering process (CSP) on the electro-chemo-mechanical properties of 10 mol% Gd-doped ceria (GDC) is investigated. High purity nanoscale GDC powder is sintered via a cold sintering process (CSP) in pure water followed by post-annealing at 1000 °C. The resultant ceramics exhibits high relative density (∼90%) with a fine grain size of ∼100 nm.

This sample illustrates comparable electrochemical properties at intermediate-high temperatures and electromechanical properties at room temperature to the material prepared via conventional firing, i.e., sintering in the air at 1450 °C. Moreover, a large creep constant, as well as a low elastic modulus and hardness, are also observed in the CSP sample.

Language: English
Year: 2020
Pages: 5612-5618
ISSN: 1873619x and 09552219
Types: Journal article
DOI: 10.1016/j.jeurceramsoc.2020.06.010
ORCIDs: 0000-0002-1161-0838 , 0000-0002-2753-4008 , Esposito, Vincenzo and Fiordaliso, Elisabetta Maria

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