Journal article
Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer
The mass transfer from target to films is incongruent for chalcogenide sulfides in contrast to the expectations of pulsed laser deposition (PLD) as a stoichiometric film growth process. Films produced from a CZTS (Cu2ZnSnS4) multi-component target have no Cu below a fluence threshold of 0.2 J/cm2, and the Cu content is also very low at low fluence from a single-component target.
Above this threshold, the Cu content in the films increases almost linearly up to a value above the stoichiometric value, while the ratio of the concentration of the other metals Zn to Sn (Zn/Sn) remains constant. Films of a similar material CTS (Cu2SnS3) have been produced by PLD from a CTS target and exhibits a similar trend in the same fluence region.
The results are discussed on the basis of solid-state data and the existing data from the literature.
Language: | English |
---|---|
Publisher: | Springer Berlin Heidelberg |
Year: | 2018 |
Pages: | 1-7 |
Journal subtitle: | Materials Science and Processing |
ISSN: | 14320630 and 09478396 |
Types: | Journal article |
DOI: | 10.1007/s00339-017-1475-3 |
ORCIDs: | Schou, Jørgen , Ganskukh, Mungunshagai , Ettlinger, Rebecca Bolt and Canulescu, Stela |