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Journal article

A New High Pressure Phase and the Equation of State of YbH2

From

Department of Physics, Technical University of Denmark1

Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

High-pressure X-ray diffraction studies have been performed on YbH2 up to 28 GPa. A first order phase transition from an orthorhombic structure to a collapsed hexagonal structure with c/a = 1.34 has been observed at about 15 GPa. The transition is accompanied by a 5.2% decrease in volume. Fitting the V(P) data to Murnaghan's equation of state yields the bulk modulus B0 = 40.2 GPa and its pressure derivative B'0 = 4.75 for the orthorhombic phase.

For the hexagonal phase we find the bulk modulus to be B = B0 = 138 GPa independent of pressure, i.e. B'0 = 0.

Language: English
Year: 1984
Pages: 503-507
ISSN: 00318949 and 14024896
Types: Journal article
DOI: 10.1088/0031-8949/29/5/016

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