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Journal article

Mesoporous Co3O4 sheets/3D graphene networks nanohybrids for high-performance sodium-ion battery anode

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School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, PR China1

Beijing National Center for Electron Microscopy, School of Materials Science and Engineering, The State Key Laboratory of New Ceramics and Fine Processing, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, PR China2

Particles and Catalysis Research Group, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia3

Department of Applied Physics, Waseda University, Tokyo 169-8555, Japan4

Nanomaterials Research Group (NRG), Physics Division, PINSTECH, P.O. Nilore, Islamabad 44000, Pakistan5

Co3O4 mesoporous nanosheets/three-dimensional graphene networks (Co3O4 MNSs/3DGNs) nanohybrids have been successfully synthesized and investigated as anode materials for sodium ion batteries (SIBs). Microstructure characterizations have been performed to confirm the 3DGNs and Co3O4 MNSs nanostructures.

It has been found that the present Co3O4 MNSs/3DGNs nanohybrids exhibit better SIB performance with enhanced reversible capacity, good cycle performance and rate capability as compared to Co3O4 MNSs and Co3O4 nanoparticles. The improved electrochemical performance is considered due to the mesoporous nature of the products, the addition of 3DGNs, 3D assembled hierarchical architecture and decrease in volume expansion during cycling.

Thus, SIB is considered as a low cost alternative to LIBs for large-scale electric storage applications..

Language: English
Year: 2014
Pages: 878-884
ISSN: 18732755 and 03787753
Types: Journal article
DOI: 10.1016/j.jpowsour.2014.09.121

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