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Journal article

Lithium Insertion in LixMn2O4, 0<x<4

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Department of Chemistry, Technical University of Denmark1

The electrochemical lithium insertion properties of highly crystalline LixMn2O4 are investigated in the approximate lithium insertion range 0 < x < 4. Using liquid and PEO based polymer electrolytes at room and elevated temperatures, it is shown that for this material, the reversibility of the lithium insertion/extraction reactions is better at the higher voltages (versus Li/Li+), and particularly at the 4 V plateau.

The lithium insertion/extraction reaction at the 1 V plateau although essentially reversible is associated with a significant voltage hysteresis.

Language: English
Year: 1996
Pages: 151-7
ISSN: 18727689 and 01672738
Types: Journal article
DOI: 10.1016/0167-2738(95)00242-1

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