Query: title:(Radiolysis of Aqueous Solutions of Ammonium Bicarbonate over a Large Dose Range), Author: Draganic

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title:(Radiolysis of Aqueous Solutions of Ammonium Bicarbonate over a Large Dose Range) Author: Draganic

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title:(Radiolysis AND of AND Aqueous AND Solutions AND of AND Ammonium AND Bicarbonate AND over AND a AND Large AND Dose AND Range)

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1 Journal article

Radiolysis of aqueous solutions of ammonium bicarbonate over a large dose range

Draganic, Z.D.; Negrón-Mendoza, A.; Sehested, K.; Vujosevic, S.I.; Navarro-Gonzales, R.; Albarran-Sanchez, M.G.; et al. (1 more)

Radiation Physics and Chemistry — 1991, Volume 38, Issue 3, pp. 317-321

Oxygen-free aqueous solutions of 0.05 mol dm-3 ammonium and sodium bicarbonate were studied after receiving various doses of Co-60 gammas (0.01-400 kGy) or 0.5-20 Gy pulses of 10 Mev electrons. Formate and oxalate were found to be the main radiolytic products, in addition to trace amounts of formaldehyde and an unidentified polymer. A large initial yield of formate in the gamma-radiolysis, G(HCOO-) = 2.2, is due to the reaction COO- + HCO3- reversible HCOO- + CO3-. The efficiency of organic synthesis within the large dose range studied is low and is explained by efficient pathways leading t...

Year: 1991

Language: English

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Radiolysis of Aqueous Solutions of Ammonium Bicarbonate over a Large Dose Range