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Journal article

Aqueous lubrication of polymers: Influence of surface modification

From

Laboratory for Surface Science and Technology, Department of Materials, Swiss Federal Institute of Technology, ETH-Hönggerberg, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland

We have investigated the influence of surface modification of an elastomer, poly(dimethylsiloxane) (PDMS), on its aqueous lubrication properties. A dramatic reduction in frictional forces has been observed upon hydrophilization by oxygen-plasma treatment or by surface coating with amphiphilic co-polymers, when PDMS was slid against PDMS in an aqueous environment.

This effect is attributed to the removal of the strong hydrophobic interaction between PDMS surfaces in water, thereby enabling the isoviscous-elastic lubrication (or soft EHL) mechanism to predominate. This study demonstrates the significance of surface modification in allowing effective soft EHL of an elastomer.

Language: English
Year: 2005
Pages: 922-930
ISSN: 18792464 and 0301679x
Types: Journal article
DOI: 10.1016/j.triboint.2005.07.017

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