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Journal article

Isotope Effects in the Bonds of beta-CrOOH and beta-CrOOD

By Nørlund Christensen, A.; Hansen, P.1,2; Lehmann, M. S.

From

Risø National Laboratory, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

Samples of orthorhombic chromium oxide hydroxide, beta -CrOOH, and the deuterated compound, beta -CrOOD, were prepared hydrothermally. The crystal structures were determined by powder profile refinement technique using neutron diffraction data. Unit cells are: beta -CrOOH: a equals 4. 862(2) A, b equals 4. 298(a) A, c equals 2. 995(1) A; beta -CrOOD: a equals 4. 873(5) A, b equals 4. 332(7) A, c equals 2. 963(2) A, with Z equals 2.

The space group is P2//1nm or Pnnm.

Language: English
Year: 1976
Pages: 299-304
ISSN: 1095726x and 00224596
Types: Journal article
DOI: 10.1016/0022-4596(76)90180-8

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