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Journal article · Conference paper

A Stability Study of Alkali Doped PBI Membranes for Alkaline Electrolyzer Cells

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Proton conductors, Department of Energy Conversion and Storage, Technical University of Denmark2

Siemens A/S3

Polybenzimidazole membranes in a linear, a crosslinked and a thermally cured form were subjected to aging in 6 M aqueous KOH at 85 ºC for periods of up to 176 days. The aged membranes were characterized with respect to weight loss, mechanical properties and ionic conductivity. The area specific conductivity was similar to a commercial Zirfon membrane and suitable for a water electrolyzer.

Some chemical degradation was seen during the aging period, but the crosslinked and the cured materials were both integral after 176 days of aging. A simplified electrolyzer test cell was operated successfully.

Language: English
Publisher: The Electrochemical Society
Year: 2014
Pages: 1175-1184
Proceedings: 226th Meeting of the Electrochemical Society (ECS) and 7th Meeting of the Mexico Section of the Electrochemical Society ECS and SMEQ Joint International Meeting
ISSN: 19386737 and 19385862
Types: Journal article and Conference paper
DOI: 10.1149/06403.1175ecst
ORCIDs: Jensen, Jens Oluf , Aili, David , Li, Qingfeng , Bjerrum, Niels Janniksen and Christensen, Erik

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