Journal article
Oxathiirans: Part 5. Oxathiiran O-Oxide a Possible Intermediate in the Reaction between Singlet Oxygen and Thiocarbonyl Compounds
In
Royal Chemical Society. Journal. Perkin Transactions 2
—
1980, Issue 1, pp. 188-190
Abstract
The reaction between thioformaldehyde and singlet oxygen has been investigated theoretically within a CNDO/B framework. Potential energy surface calculations predict a multistep mechanism involving primary formation of an oxathiiran O-oxide, which rearranges into a 1,2,3-dioxathietan system. Two possible rearrangement pathways are discussed.
The four-membered ring is tentatively suggested to decompose via a biradicaloid intermediate.
| Language: | English |
|---|---|
| Year: | 1980 |
| Pages: | 188-190 |
| ISSN: | 13645471 , 1472779x , 03009580 and 20508239 |
| Types: | Journal article |
| DOI: | 10.1039/P29800000188 |
