Book chapter
Supported ionic liquid-phase (SILP) catalysis: Heterogenization of homogeneous rhodium phosphine catalysts
In
Ionic Liquids Iiib:
—
2005, pp. 334-349
Abstract
The concept of supported ionic liquid-phase (SILP) catalysis has been demonstrated for gas- and liquid-phase continuous fixed-bed reactions using rhodium phosphine catalyzed hydroformylation of propene and 1-octene as examples. The nature of the support had important influence on both the catalytic performance, i.e. activity and selectivity, as well as stability of the SILP catalysts.
Noticeably, a high catalyst ligand content together with presence of ionic liquid solvent are prerequisites for obtaining selective rhodium phosphine SILP catalysts systems.
| Language: | English |
|---|---|
| Year: | 2005 |
| Pages: | 334-349 |
| Series: | Acs Symposium Series |
| Journal subtitle: | Fundamentals, Progress, Challenges, and Oppertunities -transformations and Processes |
| ISBN: | 0841220204 , 0841238944 , 9780841220201 and 9780841238947 |
| Types: | Book chapter |
| DOI: | 10.1021/bk-2005-0902.ch023 |
| ORCIDs: | Riisager, Anders and Fehrmann, Rasmus |
