Journal article
Studies on the thermal decomposition of lanthanum(III) valerate and lanthanum(III) caproate in argon
In
Thermochimica Acta
—
2015, Volume 612, pp. 1-9
Abstract
The decomposition of La-valerate (La(C4H9CO2)3·xH2O (x ≈ 0.45)) and La-caproate (La(C5H11CO2)3·xH2O (x ≈ 0.30)) was studied upon heating at 5 C/min in a flow of argon. Using a variety of techniques including simultaneous TG-DTA, FTIR, X-ray diffraction with both laboratory Cu Kα and synchrotron sources as well as hot-stage microscopy, it was found that both compounds melt prior to decomposition and that the main decomposition stage from the molten, anhydrous state leads to the formation of La-dioxycarbonate (La2O2CO3) via an unstable intermediate product and release of symmetrical ketones.
Final decomposition to La2O3 takes place with release of CO2.
| Language: | English |
|---|---|
| Year: | 2015 |
| Pages: | 1-9 |
| ISSN: | 1872762x and 00406031 |
| Types: | Journal article |
| DOI: | 10.1016/j.tca.2015.05.002 |
| ORCIDs: | Grivel, Jean-Claude |
