Journal article
Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2
Department of Chemistry, University of California Berkeley, California 94720, USA. jrlong@berkeley.edu.1
MOE Key Lab of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China.2
Department of Chemistry, University of California Berkeley, California 94720, USA. jrlong@berkeley.edu and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA and Department of Chemical and Biomolecular Engineering, University of California Berkeley, Berkeley, California 94720, USA.3
MOE Key Lab of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China and CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.4
CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France and CNRS, ICMCB, UPR 9048, F-33600 Pessac, France.5
Berlin Joint EPR Laboratory, Institut für Nanospektroskopie, Helmholtz-Zentrum für Materialien und Energie, 12489 Berlin, Germany.6
Helmholtz-Zentrum für Materialien und Energie, Inst. f. Methoden und Instrumente der Forschung mit Synchrotronstrahlung, 12489 Berlin, Germany.7
Department of Chemistry, University of Copenhagen, DK-2100 Copenhagen, Denmark.8
Institut Laue-Langevin, 38042 Grenoble Cedex 9, France and Institute of Chemistry, Academia Sinica, Nankang, 11529 Taipei, Taiwan, ROC.9
Institut Laue-Langevin, 38042 Grenoble Cedex 9, France.10
CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.11
...and 1 moreThe mononuclear complex (Bu4N)2[ReIVCl4(CN)2]·2DMA (DMA = N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm-1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency-domain THz EPR investigations.
| Language: | English |
|---|---|
| Publisher: | The Royal Society of Chemistry |
| Year: | 2016 |
| Pages: | 12905-12908 |
| ISSN: | 1364548x and 13597345 |
| Types: | Journal article |
| DOI: | 10.1039/c6cc05473k |
| ORCIDs: | 0000-0003-1255-2868 , Liu, Jun-Liang and Tong, Ming-Liang |
