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Journal article

The influence of UV radiation and ozone exposure on the electronic properties of poly-3-octyl-thiophene thin films

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Centro de Investigación en Óptica y Nanofísica, Departamento de Física, Campus Espinardo, Universidad de Murcia, E-30100 Murcia, Spain1

Departamento de Física Aplicada, Universidad Politécnica de Cartagena, Doctor Fleming, s/n, 30202 Cartagena, Spain2

Departamento de Electrónica, Tecnología de Computadoras y Proyectos, Universidad Politécnica de Cartagena, Plaza del Hospital s/n, 30202 Cartagena, Spain3

Department of Physics, Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7 2BW, United Kingdom4

Graphical abstractResearch highlights► The UV/ozone degradation on P3OT thin films was investigated by means of non-contact dynamic surface force microscopy and I–V transport measurements. ► A two-stage degradation process of the polymer under UV exposure has been observed, namely chemical and morphological modifications. ► In the early stages, free carrier mobility reduction as a result of the chemical modification occurred.

Followed by a strong structural modification, thickness reduction, oxygen doping and further mobility reduction.

Language: English
Year: 2010
ISSN: 18793398 and 09270248
Types: Journal article
DOI: 10.1016/j.solmat.2010.12.032

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