Query: title:(Dimethyl ether oxidation\: Kinetics and mechanism of the CH3OCH2 + O2 reaction at 296 K and 0.38-940 Torr total pressure), Author: Sehested

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title:(Dimethyl ether oxidation\: Kinetics and mechanism of the CH3OCH2 + O2 reaction at 296 K and 0.38-940 Torr total pressure) Author: Sehested

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Interpreted as:

title:(Dimethyl AND ether AND oxidation\: AND Kinetics AND and AND mechanism AND of AND the AND CH3OCH2 AND O2 AND reaction AND at AND 296 AND K AND and AND 0.38-940 AND Torr AND total AND pressure)

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1 Journal article

Dimethyl ether oxidation: Kinetics and mechanism of the CH₃OCH₂ + O₂ reaction at 296 K and 0.38-940 Torr total pressure

Sehested, J.; Møgelberg, T.; Wallington, T. J.; Kaiser, E. W.; Nielsen, O. J.

Journal of Physical Chemistry — 1996, Volume 100, Issue 43, pp. 17218-17225

The title reaction was studied at 296 K and 0.38-940 Torr total pressure using a FTIR smog chamber technique. The overall rate constant for reaction of CH3OCH2 radicals with O2 may be written, k1 = kRO2 + kprod, where kRO2 is the rate constant for peroxy radical production and kprod is the rate constant for the production of other species from reaction 1. k1 was measured relative to the pressure independent reaction of CH3OCH2 radicals with Cl2 (k4). There was no discernible effect of pressure on k1 in the range 200-940 Torr. Between 200 and 2 Torr total pressure k1 decreased by approximate...

Year: 1996

Language: English

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2 Conference paper

Dimethyl ether oxidation: Kinetics and mechanism of the CH₃OCH₂ + O₂ reaction at 296 K and 0.38-940 Torr total pressure

Sehested, J.; Møgelberg, T.E.; Platz, J.; Nielsen, O.J.; Wallington, T.J.; Kaiser, E.W.

Proceedings of the Nosa/norsac Symposium 1996 — 1996, pp. 35-37

Year: 1996

Language: English

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