Journal article
Application of the cluster variation method to ordering in an interstitital solid solution: the gamma-Fe[N]/gamma'-Fesub4Nsub1-x equilibrium
The tetrahedron approximation of the cluster variation method (CVM) was applied to describe the ordering on the fcc interstitial sublattice of gamma-Fe[N] and gamma'-Fe4N1-x. A Lennard-Jones potential was used to describe the dominantly strain-induced interactions, caused by misfitting of the N atoms in the interstitial octahedral sites.
The gamma-Fe[N]/gamma'-Fe4N1-x miscibility gap, short range ordering (SRO), and long-range ordering (LRO) of nitrogen in gamma-Fe[N] and gamma'-Fe4N1-x, respectively, and lattice parameters of gamma and gamm' were calculated. For the first time, N distribution parameters,as calculated by CVM, were compared directly to Mössbauer data for specific surroundings of Fe atoms.
Language: | English |
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Year: | 1999 |
Pages: | 1945-1953 |
ISSN: | 15431940 and 10735623 |
Types: | Journal article |
ORCIDs: | Somers, Marcel A. J. |