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journal:(Inorganica AND Chimica AND Acta) AND title:(Synthesis AND and AND Structure AND of AND Cyclic AND Hexanuclear AND Oxo-alkoxo-carboxylatoniobium\\(IV\\) AND Complexes)

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1 Journal article

Synthesis and Structure of Cyclic Hexanuclear Oxo-alkoxo-carboxylatoniobium(IV) Complexes

The reaction of trichloroacetic acid and trfluoroacetic acid with zinc-reduced niobium pentachloride in ethanolic solutions affords the compounds Nb6(mu2-O)3(mu2-O2CCX3)6(mu2-OC2H5)6(OC2H5)6 (X = Cl, F respectively). A cyclic hexanuclear structure is revealed by X-ray crystallographic studies.

Year: 2004

Language: English

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2 Article

Synthesis and structure of cyclic hexanuclear oxo-alkoxo–carboxylatoniobium(IV) complexes

The synthesis and crystal structure of novel oxo-alkoxo–carboxylato Nb(IV) complexes, Nb6(μ2-O)3(μ2-O2CCX3)6(μ2-OC2H5)6(OC2H5)6 (X=Cl, F) are described. The single-crystal X-ray structure determination carried out, revealed a closed ring of six Nb(IV) ions linked alternately by two carboxylato

Year: 2003

Language: English

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