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Journal article

Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems

From

Technical University of Denmark1

Friedrich-Alexander University Erlangen-Nürnberg2

Department of Chemistry, Technical University of Denmark3

Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid-liquid biphasic reaction system with molten [PPh4][NTf2] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.

Language: English
Publisher: The Royal Society of Chemistry
Year: 2019
Pages: 2046-2049
ISSN: 1364548x and 13597345
Types: Journal article
DOI: 10.1039/c8cc09883b
ORCIDs: 0000-0002-9523-4330 , 0000-0001-6564-3945 , 0000-0003-0413-9539 and Riisager, Anders

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