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Journal article

Atomic structure of the SbCu surface alloy: A surface X-ray diffraction study

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Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

The dissolution at 400 degrees C of an antimony layer deposited at room temperature on a Cu(111) substrate leads to a surface alloy with a p(root 3x root 3)R 30 degrees x 30 degrees superstructure and a Sb composition of 1/3.We present here a structural study of this Sb-Cu compound by surface X-ray diffraction (SXRD).

The best agreement is obtained for a Cu,Sb surface layer with Sb atoms substituting 1/3 of the Cu atoms, over an essentially unperturbed Cu(111) plane. The largest relaxation is undergone by the Sb atoms which rise by 0.32+0.02 Angstrom over the mean plane of its Cu neighbours. No substantial in-plane relaxations were observed. (C) 1999 Elsevier Science B.V.

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Language: English
Year: 1999
Pages: 42-49
ISSN: 18792758 and 00396028
Types: Journal article
DOI: 10.1016/S0039-6028(98)00868-1

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