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Journal article

Nature of Active Sites of Fe-Beta Catalyst for NOx-SCR by NH3

A correlation of the reaction rate over Fe-Beta catalysts with a concentration of specific isolated Fe3+ sites represented by an ESR signal at g ≈ 4.3 and by UV adsorption bands with λmax < 300 nm was observed. Blocking zeolite cationic positions with Ca2+ and investigation of “Fe-free” Beta-zeolites confirmed the idea of isolated Fe complexes in cationic positions being active sites for NH3-deNOx.

Language: English
Publisher: Springer US
Year: 2009
Pages: 1728-1733
ISSN: 15729028 and 10225528
Types: Journal article
DOI: 10.1007/s11244-009-9327-9

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