Journal article
Nature of Active Sites of Fe-Beta Catalyst for NOx-SCR by NH3
A correlation of the reaction rate over Fe-Beta catalysts with a concentration of specific isolated Fe3+ sites represented by an ESR signal at g ≈ 4.3 and by UV adsorption bands with λmax < 300 nm was observed. Blocking zeolite cationic positions with Ca2+ and investigation of “Fe-free” Beta-zeolites confirmed the idea of isolated Fe complexes in cationic positions being active sites for NH3-deNOx.
Language: | English |
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Publisher: | Springer US |
Year: | 2009 |
Pages: | 1728-1733 |
ISSN: | 15729028 and 10225528 |
Types: | Journal article |
DOI: | 10.1007/s11244-009-9327-9 |