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Journal article

Thermo-cleavable polymers: Materials with enhanced photochemical stability

By Manceau, Matthieu1,2; Petersen, Martin Helgesen1,2; Krebs, Frederik C1,2

From

Solar Energy Programme, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

Photochemical stability of three thermo-cleavable polymers was investigated as thin films under atmospheric conditions. A significant increase in lifetime was observed once the side-chain was cleaved emphasizing the detrimental effect of solubilizing groups on the photochemical stability of conjugated polymers.

In addition to their ease of processing, thermo-cleavable polymers thus also offer a greater intrinsic stability under illumination.

Language: English
Year: 2010
Pages: 2666-2669
ISSN: 18732321 and 01413910
Types: Journal article
DOI: 10.1016/j.polymdegradstab.2010.08.004
ORCIDs: Petersen, Martin Helgesen and Krebs, Frederik C
Keywords

Plastsolceller Polymer solar cells Solar energy Solenergi

Other keywords

Organic photovoltaics Photochemical stability Side-chain cleavage Thermo-cleavable conjugated polymers UV–visible absorbance

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