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Journal article

Meso-Molding Three-Dimensional Macroporous Perovskites: A New Approach to Generate High-Performance Nanohybrid Catalysts

By Arandiyan, Hamidreza1; Scott, Jason1; Wang, Yuan1; Dai, Hongxing2; Sun, Hongyu3; Amal, Rose1

From

Particles and Catalysis Research Group, School of Chemical Engineering1

Beijing Key Laboratory for Green Catalysis and Separation, and Laboratory of Catalysis Chemistry and Nanoscience, College of Environmental and Energy Engineering2

Department of Micro- and Nanotechnology3

Newly designed 3D highly ordered macro/mesoporous multifunctional La1–xCexCoO3 nanohybrid frameworks with a 2D hexagonal mesostructure were fabricated via facile meso-molding in a three-dimensionally macroporous perovskite (MTMP) route. The nanohybrid framework exhibited excellent catalytic activity for methane combustion, which derived from the MTMP providing a larger surface area and pore volume, uniform pore sizes, higher accessible surface oxygen concentration, better low-temperature reducibility, and a unique nanovoid 3D structure.

Language: English
Publisher: American Chemical Society
Year: 2016
Pages: 2457-2463
ISSN: 19448252 and 19448244
Types: Journal article
DOI: 10.1021/acsami.5b11050
Keywords

lanthania-ceria-cobalt macropores mesoporous walls methane combustion nanohybrid catalysis

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