Journal article
Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K
The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy.
The results are discussed in terms of reactivity trends and previous literature data.
Language: | English |
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Year: | 1992 |
Pages: | 224-229 |
ISSN: | 18734448 and 00092614 |
Types: | Journal article |
DOI: | 10.1016/0009-2614(92)80002-S |
ORCIDs: | 0000-0002-0088-3937 and 0000-0003-1167-8696 |
DIALKENES GAS-PHASE REACTIONS KINETICS MONOALKENES MONOTERPENES ORGANIC-COMPOUNDS PRODUCTS