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Journal article

Solvated Positron Chemistry. The Reaction of Hydrated Positrons with Chloride Ions

From

Risø National Laboratory, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

The reaction of hydrated positrons (caq+ with cloride ions in aqueous solutions has been studied by means of positron annihilation angular correlation measurements. A rate constant of k = (2.5 ± 0.5) × 1010 M−1 s−1 was found. Probably the reacting positrons annihilated from an e+ Cl− bound state resulting in an angular correlation curve 8% narrower than for the hydrated positron.

Carbontetrachloride in benzene seems to give similar, but smaller effect.

Language: English
Year: 1974
Pages: 100-108
ISSN: 18734421 and 03010104
Types: Journal article
DOI: 10.1016/0301-0104(74)80037-6

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