Journal article
High-pressure oxidation of propane
The oxidation properties of propane have been investigated by conducting experiments in a laminar flow reactor at a pressure of 100 bar and temperatures of 500–900 K. The onset temperature for reaction increased from 625 K under oxidizing conditions to 725 K under reducing conditions. A chemical kinetic model for high pressure propane oxidation was established, with particular emphasis on the peroxide chemistry.
The rate constant for the important abstraction reaction C3H8 + HO2 was calculated theoretically. Modeling predictions were in satisfactory agreement with the present data as well as shock tube data (6–61 bar) and flame speeds (1–5 bar) from literature.
Language: | English |
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Year: | 2019 |
Pages: | 461-468 |
ISSN: | 18732704 and 15407489 |
Types: | Journal article |
DOI: | 10.1016/j.proci.2018.07.009 |
ORCIDs: | Hashemi, Hamid , Christensen, Jakob M. , Glarborg, Peter and 0000-0001-6297-9187 |