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Journal article

Highly Anisotropic Glassy Polystyrenes Are Flexible

From

Department of Chemical and Biochemical Engineering, Technical University of Denmark1

The Danish Polymer Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark2

University of Copenhagen3

Danish National Metrology Institute4

We show that stretching polystyrene melts at a rate faster than the inverse Rouse time, followed by rapid quenching below the glass transition temperature, results in a material that is flexible and remains so for at least six months. Oriented micro/nanofibers are observed in the flexible samples after the mechanical tests.

The fibers are probably related to the highly aligned molecules in melt stretching. At room temperature, a tensile strength over 300 MPa has been achieved for the flexible polystyrenes.

Language: English
Publisher: American Chemical Society
Year: 2018
Pages: 1126-1130
ISSN: 21611653
Types: Journal article
DOI: 10.1021/acsmacrolett.8b00485
ORCIDs: Huang, Qian , Hassager, Ole , Madsen, Jeppe , Yu, Liyun , 0000-0001-6810-0268 and 0000-0002-8998-9390

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