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Conference paper

Zinc Mediated Tandem Fragmentation-Allylation of Methyl 5-Iodopentofuranosides: Synthesis of Quercitols

In Omcos 10 — 1999

By Hyldtoft, Lene1; Madsen, Robert1

From

Department of Organic Chemistry, Technical University of Denmark1

In the presence of zinc and allyl bromide methyl 5-iodopentofuranosides undergo a tandem fragmentation alkylation to give functionalized dienes. These can undergo ring-closing olefin metathesis to produce cyclohexenes which on dihydroxylation give quercitols.

Language: English
Publisher: Ministére de l'Education Nationale de la Recherche et de la Technologie
Year: 1999
Proceedings: 10th IUPAC Symposium on Organo-Metallic Chemistry Directed Towards Organic Synthesis
Types: Conference paper
ORCIDs: Madsen, Robert

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