Journal article
The reaction of hydrogen peroxide with Fe(II) ions at elevated temperatures
The rate constant for the reaction between Fe(II) ions and H2O2 has been determined at pH 0.4-2 as a function of temperature in the range 5-300-degrees-C. H2O2 was produced by irradiating the aqueous solution with a pulse of electrons. The rate constants at 20 and 300-degrees-C were determined to be 52 +/- 2 and (2.5 +/- 0.4) x 10(5) M-1 s-1, respectively, with an activation energy of 42 +/- 1 kJ mol-1 (10.1 +/- 0.2 kcal mol-1).
Language: | English |
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Year: | 1993 |
Pages: | 575-578 |
ISSN: | 0969806x and 18790895 |
Types: | Journal article |
DOI: | 10.1016/0969-806X(93)90022-M |