Journal article
Synthesis of nanoporous 1,2,4-oxadiazole networks with high CO2 capture capacity
In
Chemical Communications
—
2015, Volume 51, Issue 14, pp. 2915-2917
From
Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea. yavuz@kaist.ac.kr.1
Abstract
Developing an adsorbent to mitigate carbon dioxide without large energy penalty is highly desired. Here, we present a silylation synthetic route to form a processable and otherwise impossible porous 1,2,4-oxadiazole network, which achieves 2 mmol g(-1) of CO2 capacity owing to a nitrogen-rich structure.
This network shows high CO2-N2 selectivity, thermal stability up to 450 °C, and low heat of adsorption (26.4 kJ mol(-1)), facilitating easy regeneration.
| Language: | English |
|---|---|
| Publisher: | The Royal Society of Chemistry |
| Year: | 2015 |
| Pages: | 2915-2917 |
| ISSN: | 1364548x and 13597345 |
| Types: | Journal article |
| DOI: | 10.1039/c4cc08649j |
