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Journal article

High Temperature NMR Studies of the Glass-Crystal Transition in the Cs2S2O7-V2O5 System

By Lapina, Olga B.1; Terskikh, Viktor V.1; Shubin, Aleksander A.1; Mastikhin, V.M1; Eriksen, Kim Michael2; Fehrmann, Rasmus2

From

RAS - Boreskov Institute of Catalysis, Siberian Branch1

Department of Chemistry, Technical University of Denmark2

133Cs and 51V NMR spectra have been recorded of Cs2S2O7 and the catalytically important Cs2S2O7-V2O5 mixtures in the temperature range 20 - 550 C. A high mobility of Cs+ in the solid Cs2S2O7 was observed. The transformation from glassy state to crystalline state was investigated for the compositions Cs/V = 1, 2 and 4.

Language: English
Year: 1997
Pages: 9188-9194
ISSN: 15205207 and 15206106
Types: Journal article
DOI: 10.1021/jp971789b
ORCIDs: Fehrmann, Rasmus

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