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journal:(Journal AND of AND Physical AND Chemistry AND Part AND A\: AND Molecules AND Spectroscopy AND Kinetics AND Environment AND and AND General AND Theory) AND title:(Atmospheric AND chemistry AND of AND Dimethoxymethane AND \\(CH<sub>3</sub>OCH<sub>2</sub>OCH<sub>3</sub>\\)\: AND kinetics AND and AND mechanisms AND of AND its AND reaction AND with AND OH AND radicals AND and AND fate AND of AND the AND alkoxy AND radicals AND CH<sub>3</sub>OCHO\\(·\\)OCH<sub>3</sub> AND and AND CH<sub>3</sub>OCH<sub>2</sub>OCH<sub>2</sub>O\\(·\\))

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1 Journal article

Atmospheric chemistry of Dimethoxymethane (CH3OCH2OCH3): kinetics and mechanisms of its reaction with OH radicals and fate of the alkoxy radicals CH3OCHO(·)OCH3 and CH3OCH2OCH2O(·)

Year: 1997

Language: English

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2 Journal article

Atmospheric chemistry of dimethoxymethane (CH3OCH2OCH3): Kinetics and mechanism of its reaction with OH radicals and fate of the alkoxy radicals CH3OCHO(•)OCH3 and CH3OCH2OCH2O(•)

rate technique. The reaction of OH radicals with DMM occurs via an H-atom abstraction mechanism with 76% of the attack occurring on the -CH3 end groups and 24% on the central - CH2 - unit. The atmospheric fate of the alkoxy radicals CH3OCH2OCH2O(•) and CH3OCHO(•)OCH3 at 296 K in 700 Torr of air

Year: 1997

Language: English

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