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Journal article

Epitaxial relationships for hexagonal-to-cubic phase transition in a block copolymer mixture

From

Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Small-angle neutron scattering experiments have revealed an epitaxial relationship between the hexagonal cylinder phase, and a bicontinuous cubic phase with Ia3dBAR space group symmetry, in a poly(styrene)-poly(2-vinylpyridine) diblock copolymer mixture. Proximity to the order-disorder transition and an inelastic low frequency rheological response suggest that the cubic phase is stabilized by fluctuations.

These results identify block copolymers as model compounds for investigating the thermodynamics and dynamics of complex ''soft'' condensed matter.

Language: English
Year: 1994
Pages: 86-89
ISSN: 00319007 and 10797114
Types: Journal article
DOI: 10.1103/PhysRevLett.73.86
ORCIDs: 0000-0002-8998-9390 and Almdal, K.

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