Journal article
Influence of shear on a lamellar triblock copolymer near the order-disorder transition
The effects of a large strain (600%) reciprocating steady shear on the lamellar orientation and the order–disorder transition of a nearly symmetric poly(ethylene propylene)–poly(ethylethylene)–poly(ethylene propylene) (PEP–PEE–PEP) triblock copolymer have been studied using small-angle neutron scattering and rheological measurements.
Shearing in the ordered state produced parallel lamellae under all steady-state conditions investigated, and the lamellar-to-disorder transition temperature decreased dramatically with increasing shear rate. Both phenomena are qualitatively different from the documented behavior of PEP–PEE diblock copolymers.
However, cooling the disordered material while shearing at a relatively low deformation rate initially induces perpendicular lamellae, analogous to the diblock response. These observations are considered in the context of theory and other experimental studies.
Language: | English |
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Publisher: | The Society of Rheology |
Year: | 1997 |
Pages: | 1147-1171 |
ISSN: | 15208516 and 01486055 |
Types: | Journal article |
DOI: | 10.1122/1.550819 |
ORCIDs: | Almdal, K. and 0000-0002-8998-9390 |