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Journal article · Conference paper

High Temperature Oxidation of Ferritic Steels for Solid Oxide Electrolysis Stacks

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Mixed Conductors, Department of Energy Conversion and Storage, Technical University of Denmark2

Imaging and Structural Analysis, Department of Energy Conversion and Storage, Technical University of Denmark3

Oxidation rates of ferritic steels used as interconnector plates in Solid Oxide Electrolysis Stacks are of concern as they may be determining for the life time of the technology. In this study oxidation experiments were carried out for up to 1000 hours in hydrogen-side and oxygen-side simulated atmospheres at 800°C.

Four commercially available alloys: Crofer 22 APU, Crofer 22 H, AL29-4, E-Brite were characterized in humidified hydrogen. One alloy, Crofer 22 APU was also characterized in pure oxygen both in the as-prepared state and after application of a protective coating. Best corrosion resistance in humidified hydrogen atmosphere was observed for Crofer 22 APU and Crofer 22 H alloys.

Corrosion rates for Crofer 22 APU measured in humidified hydrogen are similar to the corrosion rates measured in air. Both coatings of plasma sprayed LSM and dual layer coatings (Co3O4/LSM-Co3O4) applied by wet spraying were found to reduce corrosion rates in pure oxygen significantly.

Language: English
Publisher: The Electrochemical Society
Year: 2013
Pages: 11-20
Proceedings: Pacific Rim Meeting on Electrochemical and Solid-State Science
ISSN: 19386737 and 19385862
Types: Journal article and Conference paper
DOI: 10.1149/05030.0011ecst
ORCIDs: Molin, Sebastian , Chen, Ming , Bentzen, Janet Jonna and Hendriksen, Peter Vang

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