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Journal article

Polymorphism and polymerisation of acrylic and methacrylic acid at high pressure

By Oswald, Iain D. H.1; Urquhart, Andrew J.2,3

From

University of Strathclyde1

Department of Micro- and Nanotechnology, Technical University of Denmark2

Colloids and Biological Interfaces, Department of Micro- and Nanotechnology, Technical University of Denmark3

The polymorphism and polymerisation of two related acids have been investigated under high pressure conditions. Acrylic acid crystallises as a new polymorph at 0.65 GPa whilst methacrylic acid crystallises in a new polymorph at a higher pressure of 1.5 GPa. Both these new polymorphs exhibit similar hydrogen bonding motifs to the low temperature phases, however, the molecular packing differs significantly.

Language: English
Publisher: The Royal Society of Chemistry
Year: 2011
Pages: 4503-4507
ISSN: 14668033
Types: Journal article
DOI: 10.1039/c1ce05295k
ORCIDs: Urquhart, Andrew J.

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