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Journal article

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts

From

Sustainable and Green Chemistry, Department of Chemistry, Technical University of Denmark1

Department of Chemistry, Technical University of Denmark2

Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark3

Presently, very few compounds of commercial interest are directly accessible from carbohydrates by using nonfermentive approaches. We describe here a catalytic process for the direct formation of methyl lactate from common sugars. Lewis acidic zeotypes, such as Sn-Beta, catalyze the conversion of mono-and disaccharides that are dissolved in methanol to methyl lactate at 160 C.

With sucrose as the substrate, methyl lactate yield reaches 68%, and the heterogeneous catalyst can be easily recovered by filtration and reused multiple times after calcination without any substantial change in the product selectivity.

Language: English
Publisher: American Association for the Advancement of Science
Year: 2010
Pages: 602-605
ISSN: 10959203 and 00368075
Types: Journal article
DOI: 10.1126/science.1183990

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