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Journal article

Fabrication of thin yttria-stabilized-zirconia dense electrolyte layers by inkjet printing for high performing solid oxide fuel cells

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Ceramic Engineering & Science, Department of Energy Conversion and Storage, Technical University of Denmark2

Applied Electrochemistry, Department of Energy Conversion and Storage, Technical University of Denmark3

Fundamental Electrochemistry, Department of Energy Conversion and Storage, Technical University of Denmark4

Mixed Conductors, Department of Energy Conversion and Storage, Technical University of Denmark5

In this work, we present how a low-cost HP Deskjet 1000 inkjet printer was used to fabricate a 1.2 mm thin, dense and gas tight 16 cm2 solid oxide fuel cells (SOFC) electrolyte. The electrolyte was printed using an ink made of highly diluted (<4 vol.%) nanometric yttria stabilized zirconia (YSZ) powders (50 nm in size) in an aqueous medium.

The ink was designed to be a highly dispersed, long term stable colloidal suspension, with optimal printability characteristics. The electrolyte was made by a multiple printing procedure, which ensures coverage of the several flaws occurring in a single printing pass. Together with an optimized sintering procedure this resulted in good adhesion and densification of the electrolyte.

The SOFC exhibited a close-to-theoretical open circuit voltage and a remarkable peak power density above 1.5 W cm-2 at 800 °C.

Language: English
Year: 2015
Pages: 89-95
ISSN: 18732755 and 03787753
Types: Journal article
DOI: 10.1016/j.jpowsour.2014.09.085
ORCIDs: Esposito, Vincenzo , Gadea, Christophe , Hjelm, Johan , Marani, Debora , Agersted, Karsten and Ramousse, Severine

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