Journal article
Tetrapotassium cis-dioxido-trans-bis(sulfato-kappa O)sulfato(kappa O-2,O ')molybdate(VI)
Abstract
The title compound, K-4[(MoO2)-O-VI(SO4)(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [(MoO2)-O-VI(SO4)(3)](4-) anions, with the Mo-VI atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane.
One of the potassium cations is nine-coordinate, while the other is eight-coordinate.
| Language: | English |
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| Publisher: | International Union of Crystallography |
| Year: | 2008 |
| Pages: | i20 |
| ISSN: | 16005368 |
| Types: | Journal article |
| DOI: | 10.1107/S1600536808003851 |
| ORCIDs: | Berg, Rolf W. |
Keywords
